鄭沐政

副教授

物理化學、量子化學
分子與材料模擬
電催化反應、非均相催化反應

信箱:mjcheng@mail.ncku.edu.tw

☎ 電話:06-2757575-65340

學歷

國立高雄師範大學 化學 學士 (1999)

國立清華大學 化學 碩士 (2002)

加州理工學院 化學 博士 (2012)

​經歷

2012-2013 加州理工學院 研究人員與博士後研究員

2013-2016 加州大學柏克萊分校 博士後研究員

2016-2016 北京清華大學 化學工程系 助理教授

2016-2019 國立成功大學 化學系 助理教授

著作

2019-迄今 國立成功大學 化學系 副教授

1.

He, M.; Li, Chunsong.; Zhang, H.; Chang, X.; Chen, J.; Goddard, W.; Cheng, M. J.*; Xu, B.;* Lu, Q.* "Oxygen induced promotion of electrochemical reduction of CO2 via co-electrolysis" Nature Commun., 2020, 11, 3844.

2.

Chang, K.; Jian, X.; Jeong, H. M.; Kwon, Y.; Lu, Q.*; Cheng, M. J.* "Improving CO2 Electrochemical Reduction to CO Using Space Confinement between Gold or Silver Nanoparticles" J. Phys. Chem. Lett., 2020, 11, 1896.

3.

Wu, Y. Y.; Hong, J. C.; Tsai, R. F.; Pan, H. R.; Huang, B. H.; Chiang, Y. W.; Lee, G. H.; Cheng, M. J.*; Hsu, H. F.* "Ligand-based Reactivity of Oxygenation and Alkylation in Cobalt Complexes Binding with (Thiolato)phosphine Derivatives" Inorg. Chem., 2020, 59, 4650.

4.

Sharia, M.; Hsu, Y. C.; Jiang, Y. T.; Lu, M. Y.; Kuo, T. C.; Cheng, M. J.*; Liu, R. S.* "Gold-catalyzed Oxidations of 1,3-Diynamides with C(1)- Versus C(3)-Regioselectivity: Catalyst-dependent Oxidative Cyclizations in the C(3)-Oxidation" Org. Lett., 2020, accepted.

5.

Kardile, R. D.; Chao, T. H.; Cheng, M. J.*; Liu, R. S.* "Gold(I)-Catalyzed Highly Diastereo- and Enantioselective Cyclization/[4+3] Annulation Cascades between 2,-(1-Alkynyl)-2- alken-1-ones and Anthranils" Angew. Chem. Int. Ed., 2020, 132, 1.

6.

Cheng, L. C.; Chen, W. C.; Santhoshkumar, R.; Chao, T. H.; Cheng, M. J.*; Cheng, C. H.* "Synthesis of Quinolinium Salts from N-Substituted Anilines, Aldehydes, Alkynes, and Acid: Theoretical Understanding of the Mechanism and Regioselectivity" Eur. J. Org. Chem., 2020, 2116.

7.

Skaria, M.; More S. A.; Kuo, T.C.; Cheng, M. J.*; Liu, R.-S..* "Gold-catalyzed Iminations of Terminal Propargyl Alcohols with Anthranils with Atypical Chemoselectivity for C(1)-Additions and 1,2-Carbon Migration" Chem. Eur. J., 2020, 26, 3600.

8.

Jeong, H. M.; Kwon, Y.; Won, J. H.; Lum, Y.; Cheng, M. J.; Head-Gordon, M.; Kang, J. K.* "Atomic-scale spacing between copper facets for the electrochemical reduction of carbon dioxide" Adv. Energy Mater., 2020, 1903423.

9.

Li, J.; Wu, D.; Malkani, A. S.; Chang, X.; Cheng, M. J.; Xu, B.;* Lu, Q.* "Hydroxide is not a promoter of C2+ product formation in electrochemical reduction of CO on Copper" Angew. Chem. Int. Ed., 2020, 59, 2.

10.

Skaria, M.; More S. A.; Kuo, T.-C.; Cheng, M. J.*; Liu, R.-S.* "Gold-catalyzed Iminations of Terminal Propargyl Alcohols with Anthranils with Atypical Chemoselectivity for C(1)-Additions and 1,2-Carbon Migration" Chem. Eur. J., 2019, 26, 3600-3608.

11.

Zeng, X.; Yan, W.; Paeth, M.; Zacate, S. B.; Hong, P.-H.; Wang, Y.; Yang, D.; Yang, K.; Yan, T.; Song, C.; Cao, Z.*, Cheng, M. J.; Liu, W.* "Copper-Catalyzed, Chloroamide-Directed Benzylic C−H Difluoromethylation " J. Am. Soc. Chem., 2019, 141, 19941.

12.

Chang, K.; Zhang, H.; Cheng, M. J.*; Lu, Q.*; "Application of Ceria in CO2 Conversion Catalysis" ACS Catal., 2019, 10, 613.

13.

Zhang, J.; Zhang, H.; Cheng, M. J.*; Lu, Q.*; "Tailoring the Electrochemical Production of H₂O₂: Strategies for the Rational Design of High-Performance Electrocatalysts" Small, 2019, 1902845.

14.

Chang, K.; Zhang, H. C.; Chen, J. G.; Lu, Q.*; Cheng, M. J.* "Constant Electrode Potential Quantum Mechanical Study of CO2 Electrochemical Reduction Catalyzed by N-Doped Graphene" ACS Catalysis, 2019, 9, 8197-8207.

15.

Luo, J. H.; Hong, Z. S.; Chao, T. H.; Cheng, M. J.* "Quantum Mechanical Screening of Metal-N4-Functionalized Graphenes for Electrochemical Anodic Oxidation of Light Alkanes to Oxygenates" J. Phys. Chem. C, 2019, 123, 19033-19044.

16.

Chen, L. Y.; Kuo, T. C.; Hong, Z. H.; Cheng, M. J.*; Goddard, W. A.* "Mechanism and Kinetics for both Thermal and Electrochemical Reduction of N2 Catalysed by Ru(0001) based on Quantum Mechanics" Phys. Chem. Chem. Phys., 2019, 21, 17605-17612.

17.

Zheng, X.; Yan, W.; Samson, B.; Chao, T. H.; Sun, X.; Cao, Z.*; Bradford, K. G.; Paeth, M.; Tyndall, S. B.; Yang, K.; Kuo, T. C.; Cheng, M. J.; Liu, W.* "Copper-Catalyzed Decarboxylative Difluoromethylation" J. Am. Soc. Chem., 2019, 141, 11398-11403.

18.

Zhang, H.; Chang, X.; Chen, J.; Goddard, W.; Xu, B.*; Cheng, M. J.*; Lu, Q.* "Computational and experimental demonstrations of one-pot tandem catalysis for electrochemical carbon dioxide reduction to methane" Nature Commun., 2019, 10, 3340.

19.

Sharma, P.; Singh, R.; Giri, S.; Chen, L. Y.; Cheng, M. J.*; Liu, R. S.* "Gold-catalyzed Oxidation of Thioalkynes to form Phenylthio Ketene Derivatives via a Non-Carbene Route" Org. Lett., 2019, 21, 5475-5479.

20.

Kulandai Raj, A. S.; Tan, K. C.; Chen, L. Y.; Cheng, M. J.*; Liu, R. S.* "Gold-catalyzed Bicyclic Annulations of 4-Methoxy-1,2-dienyl-5-ynes with Isoxazoles to Form Indolizine Derivatives via Au-p-Allene Intermediate" Chem. Sci., 2019, 10, 6437-6442.

21.

Wu, T. L.; Liao, S. Y.; Huang, P. Y., Hong, Z. S.; Huang, M. P.; Lin, C. C.; Cheng, M. J.*; Cheng, C.-H.* "Exciplex Organic Light-Emitting Diodes with Nearly 20% External Quantum Efficiency: Effect of Intermolecular Steric Hindrance between the Donor and Acceptor Pair" ACS Appl. Mater. 

Interfaces2019, 11, 19294-19300.

22.

Li, J.; Chang, K.; Zhang, H. C.; He, M.; Goddard, W. A.; Chen, J. G.; Cheng, M. J.; Lu, Q.* "Effectively increased efficiency for electro-reduction of carbon monoxide using supported polycrystalline copper powder electrocatalysts" ACS Catal., 2019, 9, 4709-4718.

23.

Paeth, M.; Tyndall, S. B.; Chen, L. Y.; Hong, J. C.; Carsom, W. P.; Liu, X.; Sun, X.; Liu, J.; Yang, K.; Hale, E. M.; Tierney, D. L.; Liu, B.; Cao, Z.*; Cheng, M. J.; Goddard, W. A.*; Liu, W.* "Csp3-Csp3 Bond-Forming Reductive Elimination from Well-Defined Copper(III) Complexes" J. Am. Soc. Chem., 2019141, 3153−3159.

24.

Zhang, H.; Li, J.; Cheng, M. J.*; Lu, Q.* "CO Electroreduction: Current Development and Understanding of Cu-Based Catalyst" ACS Catalysis2019, 9, 49-65.

25.

Singh, R. R.; Skaria, M.; Chen, L. Y.; Cheng, M. J.*; Liu, R. S.* "Gold-catalyzed (4+3)-Annulations of 2-Alkenyl-1-Alkynylbenzenes with Anthranils with Alkyne-Dependent Chemoselectivity: Skeletal Rearrangement versus Non-Rearrangement" Chem. Sci.2019, 10, 1201–1206.

26.

Hsieh, Y. C.; Wu, C. F.; Chen, Y. T.; Fang, C. T.; Wang, C. S.; Li, C. H.; Chen, L. Y.; Cheng, M. J.; Chueh, C. C.*; Chou, P. T.*; Wu, Y. T.* "5,14-Diaryldiindeno[2,1-f:1′,2′-j]picene: A New Stable [7]Helicene with a Partial Biradical Character" J. Am. Chem. Soc.2018, 14014357–14366.

27.

Cao, Z; Zacate, S. B.; Sun, X.; Liu, J.; Hale, E. M.; Carson, W. P.; Tyndall, S. B.; Xu, J.; Liu, X.;  Liu, X.; Song, C.; Luo, J. H.; Cheng, M. J.; Wen, X.*; Liu, W.* "Tuning Gold Nanoparticles with Chelating

Ligands for Highly Efficient Electrocatalytic CO2 Reduction" Angew. Chem, 2018, 130, 12675-12679.

28.

Zhang, H.; Goddard, W. A.; Lu, Q.;* Cheng, M. J.* "The Importance of Grand-Canonical Quantum Mechanical Methodsto Describethe Effect of Electrode Potential on the Stability of Intermediates Involvedin both Electrochemical CO2 Reduction and Hydrogen Evolution"  Phys. Chem. Chem. Phys., 201820, 2549-2557.

29.

Luo, J.-H.; Chen, L.-Y.; Nguyen, D. N.; Guo, D.; An, Q.;* Cheng, M. J.* "Dual Functions of Water in Stabilizing the Metal-Pentazolate Hydrates [M(N5)2(H2O)4]•4H2O (M = Mn, Fe, Co, and Zn) High-Energy Density Materials"  J. Phys. Chem. C , 2018, 122, 21192-21201.

30.

Yan, J.-A.; Yang, Z. K.; Chen, Y. S.; Chang, Y. H.; Lyu, C. L.; Luo, C. G.; Cheng, M. J.* ; Hsu, H. F.* "Activation of O-H and C-O Bonds in Water and Methanol by a Vanadium-bound Thiyl Radical" Chem. Eur. J. , 2018, 24, 15190-15194.

31.

Paeth, M.; Carson, W.; Luo, J. H.; Tierney, D.; Cao, Z.; Cheng, M. J.;* Liu, W.* "Copper Mediated Trifluoromethylation of Benzylic Csp3-H Bonds" Chem. Eur. J. , 201824, 11559-11563.

32.

Chang, K.; Chen, J.; Lu, Q.;* Cheng, M. J.* "Grand Canonical Quantum Mechanical Study of the Effect of the Electrode Potential on N-Heterocyclic Carbene Adsorption on Au Surfaces" J. Phys. Chem. C, 2017, 121, 24618-24625.

33.

O'Leary, W. C.; Goddard, W. A* ; Cheng, M. J. "Dual-Phase Mechanism for the Catalytic Conversion of n-Butane to Maleic Anhydride by the Vanadyl Pyrophosphate Heterogeneous Catalyst" J. Phys. Chem. C2017, 121, 24069-24076.

34.

Hung, C.-H.;Gandeepan, P.; Cheng, L. C.; Chen, L. Y.; Cheng, M. J.;* Cheng, C. H.*  "Experimental and Theoretical Studies on Iron-Promoted Oxidative Annulation of Arylglyoxal with Alkyne: Unusual Addition and Migration on the Aryl Ring" J. Am. Chem. Soc.2017139, 17015-17021.

35.

Chang, K.; Chen, J.; Lu, Q.;* Cheng, M. J.* "Quantum Mechanical Study of N-Heterocyclic Carbene Adsorption on Au Surfaces" J. Phys. Chem. A, 2017, 121, 2674-2682.

36.

Liu, W.; Cheng, M. J.; Nielsen, R. J.; Goddard, W. A.*; Groves, J. T.* "Probing the C-O bond-formation step in metalloporphyrin catalyzed C-H oxygenation reactions" ACS Catalysis2017, 7, 4182-4188.

37.

Liu, K.; Liu, K. K.; Cheng, M. J.*; Han, M. H.* "Theoretical and Experimental Study of the Nickel-Catalyzed Isomerization of 2-Methyl-3-butenenitrile and the Effect of a Lewis Acid" J. 

Organometallic Chem2016822, 29-38.

38.

Cheng, M. J.; Clark, E. L.; Pham, H. H.; Bell, A. T.*; Head-Gordon, M.* "Quantum Mechanical Screening of Single-Atom Bimetallic Alloys for the Selective Reduction of CO2 to C1 Hydrocarbons" ACS Catalysis2016, 6, 7769-7777.

39.

Cheng, M. J.; Klaus, S.; Trotochaud, L.; Head-Gordon, M.; Bell, A. T.* "Experimental and Computational Evidence for Highly-Active Fe Sites Present on the Surface of Oxidized Gold for the Electrocatalytic Oxidation of Water in Basic Media" ChemElectroChem, 2016, 3, 66-73. 

40.

Pham, H. H.; Cheng, M. J.; Frei, H.; Wang, L. W.* "Surface Proton Hopping and Fast-Kinetics Pathway of Water Oxidation on Co3O4 (001) Surface "ACS Catalysis, 20166, 5610-5617.

41.

Cheng, M. J.; Goddard, W. A.* "The Mechanism of Alkane Selective Oxidation by the M1 Phase of Mo-V-Nb-Te Mixed Metal Oxides: Suggestions for Improved Catalysts" Top. Catal., 2016, 59, 1506-1517.

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